Diphenyl(pyridin-2-yl)phosphane selenide

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Diphenyl(pyridin-2-yl)­phosphane selenide

In the title compound, C(17)H(14)NPSe, the P atom has a distorted tetra-hedral environment resulting in an effective cone angle of 163°. In the crystal, C-H⋯Se/N/π inter-actions are observed.

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2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide

The title compound, C(12)H(23)PSe, represents the first structure of a phosphine containing the bicyclic 2-phospha-bicyclo-[3.3.1]nonane (VCH) unit. It contains two chiral centres per mol-ecule which can be either R,R- or S,S and crystallizes as a centrosymmetric, racemic micture of the enanti-omers. The P-Se bond distance of 2.1360 (16) Å is typical for these compounds. The Tolman cone angle (...

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Bis(2-meth­oxy­phen­yl)(phen­yl)phosphine selenide

The title compound, C(20)H(19)O(2)PSe or SePPh(2-OMe-C(6)H(3))(2), crystallizes with two distinct orientations for the meth-oxy groups. The Se=P bond is 2.1170 (7) Å and the cone angle is 176.0°. Intra-molecular C-H⋯Se inter-actions occur. In the crystal, mol-ecules are linked by inter-molecular C-H⋯Se inter-actions.

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[Bis(pyridin-2-yl) selenide-κ2 N,N′]tetra­chloridotin(IV)

The title compound, [SnCl(4)(C(10)H(8)N(2)Se)], was obtained by the reaction of 2,2'-dipyridyl diselenide with tin tetra-chloride. The Sn(IV) ion is coordinated by two N atoms [Sn-N = 2.266 (2) and 2.274 (2) Å] from the bis-(2-pyrid-yl)selenide ligand and four chloride anions [Sn-Cl = 2.3717 (6)-2.3939 (6) Å] in a distorted octa-hedral geometry. The central six-membered chelate ring has a boat ...

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5-Benzyl­idene-2,3-diphenyl-1,2-selenaphosphole-2-selenide

The title compound, C(23)H(19)PSe(2), has a central five-membered twist C(3)PSe ring conformation. One phenyl ring substituent, attached to an sp(2) carbon, is approximately coplanar with the C(3)PSe ring whilst the other organic substituents, attached to an sp(3)-carbon and a P(V) atom, lie on the same side of the ring.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s160053681204007x